Washington, Dec 11 : After Angelina Jolie, Hollywood hunk Brad Pitt has also confessed that the couple fell in love while he was still married to Jennifer Aniston.

In an interview to Rolling Stone magazine, the Fight Club star confessed that he fell in love with Jolie on the sets of 2004 film `Mr and Mrs Smith'.

When asked why Mr. & Mrs. Smith was his favourite Angelina film, Brad answered, "Because you know... six kids. Because I fell in love," reports The Sun.

Two months earlier, the `Tomb Raider' star had revealed that they started to develop feelings towards each other during the making of the blockbuster.

The duo had always insisted their relationship started after Brad''s marriage with `Friends' star Jennifer came to an end. (ANI)